Posts Tagged ‘materials chemistry’

Brilliant 10: Michael Bartl, the Nano-Ranger

He discovered the secret to ultrafast computing in the shell of a beetle

Michael Bartl’s office is overrun with dead beetles. They’re not the remains of an infestation. The green corpses of Lamprocyphus augustus, native to Brazil, led Bartl to one of the most sought-after crystals in optical science.

Since the late 1980s, physicists have dreamed of building a so-called ideal photonic crystal, a diamond-shaped repeating nanostructure they could use to manipulate the behavior of light. Scientists have only been able to make one that controls infrared light. Crystals that use visible light instead could make solar cells more efficient by capturing additional photons or could make for more-powerful lasers by better amplifying light. And since light travels more quickly than electrons, such crystals could someday enable the first ultrafast, light-based computers. Sounds great, right? But no one has been able to make diamond-based crystals composed of patterns small enough to interact with visible light’s short wavelengths.

One day in 2006, as Bartl was trying—and failing—to synthesize a photonic crystal in his lab, he got an e-mail from a local high-school student who had looked him up online and hoped to use his scanning light microscope for her science-fair project, a study of the nanoscale structure of beetle shells. When she showed him L. augustus, he saw immediately that its scales were exactly the same color from every angle, a sign that they were manipulating visible light from all angles. That moment changed his career. He dropped everything to study the insect’s scales, assembling images of thin slices to make a digital 3-D image of the structure. “That’s when we discovered the beetles make a diamond-shaped photonic crystal,” he says— one that manipulates visible light.

Using a replica of the beetle’s scales, Bartl is now working to build a diamond nanostructure using molecular self-assembly so that it can be easily mass-produced in a suitable material. Bartl, a calm and soft-spoken Austrian, is the sort that seeks out difficult challenges. (He’s an avid runner. In 2004 a half- marathon in Santa Barbara involved a climb of nearly 4,000 feet, and a 1999 race took him up an Austrian mountain.) He just didn’t expect he would be using nature to meet them. He thinks the insect world may hold the key to other breakthroughs, so he is studying the scales of other types of exotic beetles. “The more you look at these biological structures,” he says, “the more you find out how amazing they are.”

See the rest of PopSci's Brilliant 10 for 2010.

Tiny Titanium Origami Highlights New Method Of Micro-Construction

While three-dimensional printing has come a long way, engineers still struggle with fabricating objects smaller than a quarter. In those small structures, the upper layers crush and distort the weak lower ones. To solve this problem, researchers at the University of Illinois have come up with a novel solution: print out a flat sheet, and then fold it, origami style, into the desired shape. Creating this origami crane as proof of concept, the researchers have hit upon a technique that could produce any number of microscopic medical or mechanical devices through folding, rather than layered printing.

The researchers start by printing out a flat sheet of titanium hydride. Normally, this material is too rigid to fold, but the printing process imbues the "ink" with a number of solvents that soften it up enough for manipulation. In the case of the crane, it took 15 steps to go from a flat sheet to a finished bird.

This material is malleable enough to fold, but strong enough to retain its shape once the folding process is complete. Additionally, titanium hydride can be treated after folding to become pure metallic titanium. That way, a potential medical device could be folded into the desired shape, and then transformed into a substance that the body wouldn't reject.

The scientists have just begun to explore the implications of this technique, so it might be a while before a doctor actually uses a stent or implant created by folding titanium hydride. However, Japanese legend holds that if someone folds 1,000 origami cranes, a real crane will grant their wish. So all the researchers need to do is fabricate 999 more of these, and just wish for a practical application for this technology to arrive within a year. Easy!

Insanely Hi-Res Z-Contrast Photos Can Determine Which Atoms Are Which

And you thought the macros on your camera was good because you got a sweet close up of a flower? Well, the scientists over at Oak Ridge National Laboratory zoom in so tight they can distinguish atoms of different elements. Using a special z-contrast scanning electron microscope, researchers at Oak Ridge took the first picture detailed enough to differentiate different atoms within a chemical compound. This super-high resolution scanning may play an important role in the future of materials chemistry, where tiny atomic differences can have profound effects on the properties of different chemical compounds.

This is not the first picture of an atom, nor is it the first picture of atoms from different elements. However, in those older photos, the atoms were arranged beforehand by scientists. But in the Oak Ridge pic, the material was created chemically, and the picture was still able to identify individual atoms.

The material in the photo, called boron nitride, consists of boron, nitrogen, and oxygen, with some carbon atoms inserted in place of boron to serve as a control in the image. The electron scanning microscope that took the picture used a 60 kilovolt beam. That's a very low energy for this kind of microscope, because if the beam were any more powerful, it would displace some of the atoms in the compound.

Right now, scientists can only determine the chemical arrangements in a material through chemistry. By developing a technique for taking pictures like this, material chemists and engineers of the future will be able to simple look at the chemical compound to see its geometry and composition.

[Oak Ridge National Laboratory]

Insanely Hi-Res Z-Contrast Photos Can Determine Which Atoms Are Which

And you thought the macros on your camera was good because you got a sweet close up of a flower? Well, the scientists over at Oak Ridge National Laboratory zoom in so tight they can distinguish atoms of different elements. Using a special z-contrast scanning electron microscope, researchers at Oak Ridge took the first picture detailed enough to differentiate different atoms within a chemical compound. This super-high resolution scanning may play an important role in the future of materials chemistry, where tiny atomic differences can have profound effects on the properties of different chemical compounds.

This is not the first picture of an atom, nor is it the first picture of atoms from different elements. However, in those older photos, the atoms were arranged beforehand by scientists. But in the Oak Ridge pic, the material was created chemically, and the picture was still able to identify individual atoms.

The material in the photo, called boron nitride, consists of boron, nitrogen, and oxygen, with some carbon atoms inserted in place of boron to serve as a control in the image. The electron scanning microscope that took the picture used a 60 kilovolt beam. That's a very low energy for this kind of microscope, because if the beam were any more powerful, it would displace some of the atoms in the compound.

Right now, scientists can only determine the chemical arrangements in a material through chemistry. By developing a technique for taking pictures like this, material chemists and engineers of the future will be able to simple look at the chemical compound to see its geometry and composition.

[Oak Ridge National Laboratory]


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